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Using the Boc-strategy, a step-by-step synthesis on the PAM solid supportof three aza-, iminoaza- and reduced aza-peptide homologues is described.From the same hydrazinocarbonyl peptide-PAM precursor, the coupling ofeither a Boc-amino acid or a Boc-amino aldehyde gives rise to an aza-peptideor an iminoaza-peptide containing theCα-CO-NH-Nα-CO-NH-Cα orCα-CH=N-Nα-CO-NH-Cα surrogate of the peptide motif,...
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