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Using vibrational spectroscopy and SIMS, we determined the solubility and speciation of C–O–H–N dissolved volatiles in mafic glasses quenched from high pressure under reduced conditions, with fO2 from −3.65 to +1.46 relative to the iron–wüstite buffer (IW). Experiments were performed on martian and terrestrial basalts at 1.2GPa and 1400°C in graphite containers with variable availability of H2O, and...
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