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The thermal decomposition of trans-K[Cr(C2O4)2(OH2)2]·3H2O and cis-K[Cr(C2O4)2(OH2)2] has been studied using the TG–MS technique. The measurements were carried out in an argon atmosphere over the temperature range of 293–873 K. The influence of the complex structures and configurational geometry on the stability of the transition products and the pathways of thermal transformations has been discussed...
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