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The hydrolytic degradation of four β-sultams was investigated using isothermal microcalorimetry to determine kinetic and enthalpic data. Firstly, all four compounds were analysed in the solid-state at 310 K, with a significant substituent-based stabilising/destabilising effect being observed. Secondly, the four compounds were analysed in the presence of pH 4 acetate buffer, at three temperatures (298,...
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