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The polymerization of 2-(9-carbazolyl)methylthiirane (CMT) in the presence of cyclic oligo(potassium glycidoxide) as the macroinitiator activated 18-crown-6 leads to star-shaped polythioether with a cyclic core and mainly six arms, and with molecular masses relatively near to the calculated ones. A particularly intensive blue photoluminescence is shown by poly(CMT) in tetrahydrofuran solution at the...
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