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Direct carbon fuel cells (DCFC) that employ solid oxide electrolytes and molten Sb anodes are promising for the efficient generation of electricity using a range of carbonaceous fuels. The present study examined the etching of yttria-stabilized zirconia (YSZ) and gadolinia-doped ceria (GDC) electrolytes by Sb2O3 produced during fuel-cell operation. Migration of Sb along grain boundaries and electrolyte...
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