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NiPS3, one of the most promising catalysts among transition metal trichalcogenidophosphates (MTPs) in hydrogen evolution reaction (HER) electrocatalysis, is still inhibited by its unsatisfactory activity originating from its semiconducting nature and inert basal plane. Here, it is proposed, for the first time, to engineer the basal surface activity of NiPS3 by nonmetal heteroatom doping, and predict...
Developing efficient water-splitting electro-catalysts with high mass activity is in urgent need for large-scale sustainable production of hydrogen but, still remains as a big challenge. Herein, we report a one-pot method to fabricate a series of core@shell Ni@RuM (M=Ni or Co) nanocrystals (NCs) with Ni as the core and tunable RuM (M=Ni or Co) as the alloy shell for efficient water-splitting catalysis...
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