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Three multifunctional ligands containing 2,5‐disubstituted‐oxadiazole units including an ortho/meta/para‐substituted pyridine moiety have been synthesized. The reactions of the ligands with zinc(II) acetate in pyridine gave crystalline complexes with the general formula [Zn(Li)2py2]. On the other hand, zinc‐assisted self‐assembly of the ligands in the absence of pyridine led to stable glassy networks...
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