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The LiNiO 2 –NiO 2 pseudo-binary system has been studied using the CALPHAD approach coupled with ab initio calculations. The O1 phase, the H1-3 phase and the ordered and disordered O3 phases, are thermodynamically described using sublattice models. The phase equilibria and thermodynamic data are well reproduced by the present thermodynamic modeling. Based on the experimental information...
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