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Pnictide oxides exhibit a rich crystal chemistry, which is much more than the ZrCuSiAs structure of LaFeAsO, the mother‐structure of the 1‐1‐1‐1 materials. The present micro‐review focuses on different dimensionalities in the oxidic and the pnictide substructures, largely extending the structural building units. The second part concerns BaAl4/ThCr2Si2 superstructures, which extend the crystal chemistry...
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