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Several novel chiral side-chain liquid crystalline (LC) polysiloxane resins containing epoxy groups and mesogenic components have been graft copolymerized by a one-step hydrosilylation reaction with poly(methylhydrogeno)siloxane, an epoxy monomer 2-(allyloxymethyl)oxirane, and chiral fluorinated liquid-crystalline monomers 4′-(4-(allyloxy)benzoyloxy)biphenyl-4-yl 6-(perfluorooctanoyloxy)hexahydrofuro[3,2-b]furan-3-yl...
Several liquid crystalline polysiloxanes (Pa–Pf) bearing fluorinated mesogenic units were synthesized using poly(methylhydrogeno)siloxane, 4′-(4-undec-10-enoyloxy-benzoyloxy)-biphenyl-4-yl 4-fluoro-benzoate and 4′-propionyloxy-biphenyl-4-yl 4-allyloxy-benzoate, and effect of fluorinated mesogenic units on phase behaviors of the fluorinated LC polysiloxanes was studied as well. The samples Pa and Pb...
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