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The molecular structures of an adhesion promoter, polybutadiene-modified epoxy (PBME) rubber at surfaces and buried interfaces with gold (Au) were studied using sum frequency generation (SFG) vibrational spectroscopy. The SFG spectra showed that the soft butadiene part of PBME can segregate to the surfaces and buried interfaces in two base formulations. This is consistent with its application as an...
The surface sum frequency generation (SFG) vibrational spectroscopic spectra of PMA and PMMA films prepared from solvents with different qualities were found different. This suggests that the surface molecular structures of PMA and PMMA films were affected by the solvent quality. A simple phenomenological model was used to describe the chain conformational order at the polymer surface by correlating...
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