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New Π-conjugated multi-branched molecules were synthesized through the Horner-Emmons reaction using alkyl-substituted, 3,4-ethylenedioxythiophene-based, thiophenyl aldehydes and octaethyl benzene-1,2,4,5-tetrayltetrakis(methylene) tetraphosphonate as the core unit; these molecules have all been fully characterized. The two multi-branched conjugated molecules exhibited excellent solubility in common...
Three-armed, star-shaped molecules containing 4-(N,N-diphenyl)amino-4′-nitroazobenzene chromophores were synthesized to study the diffraction behavior after inscribing surface relief gratings. The two molecules differed in terms of their mode of chromophore attachment to the core. In compound5, they were bound to the core laterally through alkylene spacers, whereas the chromophores were tethered perpendicularly...
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