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Developing an efficient and non‐precious pH‐universal hydrogen evolution reaction electrocatalyst is highly desirable for hydrogen production by electrochemical water splitting but remains a significant challenge. Herein, a hierarchical structure composed of heterostructured Ni2P‐Ni12P5 nanorod arrays rooted on Ni3S2 film (Ni2P‐Ni12P5@Ni3S2) via a simultaneous corrosion and sulfidation is built followed...
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