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The ammonothermal synthesis is a promising instrument for synthesis and crystal growth of the metastable semiconductor InN. Two novel intermediates within the ammonothermal InN crystal growth have been synthesized, namely pentaamminechloridoindium dichloride, [In(NH3)5Cl]Cl2, and indium amide difluoride, InF2(NH2). Both intermediates were obtained under ammonothermal conditions (Tmax=663 K, pmax=118...
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