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Vielseitige Zucker: Von Kohlenhydraten abgeleitete Silanreagentien sind die Reduktionsmittel in nickelkatalysierten reduktiven Kupplungen von Aldehyden und Alkinen und der Glycosyldonor für die anschließende intramolekulare Glycosylierung. Bei diesem Ansatz wird das Kohlenstoffgerüst des Aglycons mit seinen stereochemischen Merkmalen aufgebaut und zugleich die Glycosylierungsstelle geschaffen.
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