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Labil und doch stabil: Die labile Bi‐N‐Bindung war kein Hinderungsgrund für die erfolgreiche Synthese des ersten Dichlorcyclodibismadiazans aus TerphenylN(H)BiCl2 und der Base DBU. Das Produkt zersetzt sich erst bei 205 °C und ist in einer Argonatmosphäre bei Raumtemperatur sowohl in Substanz als auch gelöst in Benzol stabil. Im Bildhintergrund ist die dreidimensionale Elektronendichte zusammen mit...
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