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The general concept of spin-dependent polyethylene polymerization by the bis(imino)pyridine iron(II) complexes is presented. It is stressed that the driving force of ethylene polymerization in the presence of bis(imino)pyridyliron(II) is a high exothermic effect of the monomer binding to the catalyst in all three low-lying spin states. The origin of low activation barrier in termination reaction between...
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