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Pd nanoparticles was loaded on silica lamella via layered silicate through a simple ion-exchange and in situ reduction method. The obtained Pd/silica composite has Pd nanoparticles with highly uniform size dispersed well on the silica lamella. The Pd/silica composite is active and recoverable catalyst for the hydrogenation reaction and the reaction can be completed in a short time of 2h at room temperature...
Power of two: A widely functional‐group tolerant, selective and rapid oxidative cross‐coupling between two structurally similar azoles has been carried out by using a palladium/copper co‐catalytic twofold CH activation method (see scheme).
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