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Disulfide/thiolate interconversion supported by transition‐metal ions is proposed to be implicated in fundamental biological processes, such as the transport of metal ions or the regulation of the production of reactive oxygen species. We report herein a mononuclear dithiolate CoIII complex, [CoIIILS(Cl)] (1; LS=sulfur containing ligand), that undergoes a clean, fast, quantitative and reversible Co...
Ein [Cu2S2}‐Kern konnte mithilfe eines neuartigen Liganden stabilisiert werden, der die Bildung zweikerniger Zentren begünstigt. Der entstehende Dikupferkomplex wurde in zwei formalen Oxidationszuständen (siehe Bild) isoliert, die die wesentlichen strukturellen, spektroskopischen und funktionellen Eigenschaften des CuA‐Zentrums nachahmen.
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