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An electrode construct was fabricated in which a self-assembled monolayer containing a novel norbornylogous bridge was covalently attached to flavin adenine dinucleotide (FAD), the redox active centre of several oxidase enzymes. The electrochemistry of the construct was investigated before and after the reconstitution of glucose oxidase around the surface bound FAD. Rapid rates of electron transfer...
The heterogeneous electron-transfer properties of ferrocenemethylamine coupled to a series of mixed 4-carboxyphenyl/phenyl monolayers on glassy carbon (GC) and gold electrodes were investigated, by cyclic voltammetry, in aqueous buffer solutions. The electrodes were derivatized in a step-wise process. Electrochemical reduction of mixtures of 4-carboxyphenyl and phenyl diazonium salts on the electrode...
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