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A new family of ionic liquid based electrolytes ([EMImCl/(TiCl4)1.4]/(δ-MgCl2)x) for electrochemical applications is proposed. These materials are obtained by direct reaction of 1-ethyl-3-methylimidazolium chloride (EMImCl) with titanium(IV) chloride (TiCl4), and doped with increasing amounts of δ-MgCl2. Modulated differential scanning calorimetry (MDSC) measurements show that in these electrolytes...
The synthesis, physicochemical properties and conductivity mechanism of a family of ionic liquid-based electrolytes for use in secondary Mg batteries are reported. The electrolytes are obtained by dissolving controlled amounts of δ-MgCl2 salt into the ionic liquid (IL) 1-ethyl-3-methylimidazolium tetrafluoroborate (EMImBF4) which acts as a solvent. δ-MgCl2 consists of an inorganic ribbon of Mg atoms...
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