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Protein‐Phosphane: Bei einem neuartigen, hoch effizienten und selektiven Verfahren zur Proteinmodifizierung (siehe Schema) werden Cysteinreste an ein Maleimid gebunden, das ein Hydrazid enthält. Danach werden Aldehyd‐Phosphane über die Bildung eines Hydrazons verknüpft. Ein‐ und zweizähnige Phosphanliganden wurden so an Proteine gekuppelt, und in einem Fall wurde durch Koordination an Rhodium ein...
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