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From mono- and bis-benzimidazolium salts, three new Se–NHC adducts were synthesized using water as a solvent. Single crystals analyses indicated that crystal structures of Se–NHC adducts are stabilized by face-to-face and edge-to-face π–π interactions in the absences of any potential hydrogen bonds donor and acceptor. Benzimidazolium salts and respective Se–NHC adducts were preliminarily screened...
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