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Group parameters of low-boiling-point compounds (gaseous compounds) for a group-contribution equation of state based on a hole theory previously proposed are newly determined to predict the phase equilibria for gaseous compound+solvent systems at high temperatures and pressures. The gaseous compounds studied in this work are ethane, propane, butane, carbon dioxide and ammonia. The solvents are hydrocarbons,...
A group-contribution equation of state (EOS) based on the hole theory has been developed to predict the phase equilibria of mixtures containing polar substances at high temperatures and pressures. The calculated systems are classified to be six water+hydrocarbon, seven n-alcohol+hydrocarbon, two water+n-alcohol systems and four water+hydrocarbon+hydrocarbon ternary systems. The groups cited are CH...
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