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Using a simplified model, we calculate resonant X-ray emission (RXE) spectra with Ce 2p to 5d excitation and Ce nl to 2p de-excitation for mixed valence Ce compounds, where nl is 3d or valence states. If the core–hole effect is large to play an important role in the Ce L 3 XAS, the RXE spectral features for nl=3d and valence states are significantly different, but if it is negligibly small,...
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