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Doping of lithium salts into the plastic crystal phase of succinonitrile does significantly increase ionic conductivity. This paper investigates the effect of anion (TFSA, Tf and BF 4 ) on the conductivity and diffusion of the mobile species using impedance spectroscopy and NMR. Room temperature conductivities up to 2.1×10 −4 S cm −1 were obtained with 1 mol% lithium bis(trifluoromethanesulfonyl)amide...
Doping of lithium salts and acids into the plastic crystal phase of succinonitrile has shown for the first time of the possibility of creating solid state electrolytes based on plastic crystalline solvents where the matrix itself is neutral and hence not intrinsically conductive. These materials illustrate the concept of a solid state electrolyte solvent. Room temperature conductivities up to 3.4x10...
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