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Absolute control over polymer stereo‐ and sequence structure is highly challenging in polymer chemistry. Here, an acid‐orthogonal deprotection strategy is proposed for the iterative synthesis of a family of unimolecular polymers starting with enantiopure serines, featuring precise sequence, stereoconfiguration and side‐chain functionalities that cannot be achieved using traditional polymerization...
Absolute control over polymer stereo‐ and sequence structure is highly challenging in polymer chemistry. Here, an acid‐orthogonal deprotection strategy is proposed for the iterative synthesis of a family of unimolecular polymers starting with enantiopure serines, featuring precise sequence, stereoconfiguration and side‐chain functionalities that cannot be achieved using traditional polymerization...
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