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A strategy to access diverse multisubstituted acrylamides from cyclic ketones is realized via palladium/norbornene‐catalyzed α‐carbamoylation and ipso‐functionalization of the corresponding enol triflates. The development of bulky C2 secondary amide‐substituted norbornene cocatalysts is the key to achieve the desired reactivity and selectivity. Readily available carbamoyl chlorides serve as effective...
A strategy to access diverse multisubstituted acrylamides from cyclic ketones is realized via palladium/norbornene‐catalyzed α‐carbamoylation and ipso‐functionalization of the corresponding enol triflates. The development of bulky C2 secondary amide‐substituted norbornene cocatalysts is the key to achieve the desired reactivity and selectivity. Readily available carbamoyl chlorides serve as effective...
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