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Infrared nonlinear optical (IR NLO) crystals play a significant role in the development of IR laser technology. But rationally designing a new IR NLO crystal remains a huge challenge because of the unpredictability of inorganic structures. Herein, inspired by phase transformation of the famous BaB2O4 (BBO) crystal, a temperature‐induced centrosymmetric (CS) to noncentrosymmetric (NCS) transformation...
Infrared nonlinear optical (IR NLO) crystals play a significant role in the development of IR laser technology. But rationally designing a new IR NLO crystal remains a huge challenge because of the unpredictability of inorganic structures. Herein, inspired by phase transformation of the famous BaB2O4 (BBO) crystal, a temperature‐induced centrosymmetric (CS) to noncentrosymmetric (NCS) transformation...
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