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A single chain magnet (SCM), catena-[Fe II (ClO 4 ) 2 {Fe III (bpca) 2 }]ClO 4 (1) includes three nitromethane molecules per a Fe(II)–Fe(III) unit as crystallized solvent which occupy the pores surrounded by four chains. Compound 1 can release or reabsorb these MeNO 2 molecules like “sponges” possessing the chain structure of 1, accompanied by...
A new Fe(II)–Fe(III) alternating single chain magnet, catena-[Fe II (ClO 4 )(H 2 O){Fe III (bmpca) 2 }](ClO 4 ) 2 , was synthesized using methyl-substituted bpca − ligand, bmpca − (Hbpca and Hbmpca denote bis(2-pyridylcarbonyl)amine and bis(4-methyl-2-pyridylcarbonyl)amine, respectively). The one-dimensional complex shows the...
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