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Thermodynamic properties of schapbachite (α-AgBiS2) in the phase assemblage α-AgBiS2–AgBi3S5–Bi have been studied by an EMF-technique. The EMF-measurements were made on the galvanic cell Pt(−)|Ag|AgI|AgBiS2+AgBi3S5+Bi|C|Pt(+), over the temperature range from (429 to 699)K. According to the EMF vs. temperature relations obtained, the enthalpy of the phase transformation from β-AgBi1+xS2 to α-AgBi1+...
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