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The core–shell type nanoparticles composed of poly(γ-benzyl-l-glutamate) (PBLG) as hydrophobic inner core and poly(ethylene oxide) (PEO) as hydrophilic outer shell are formed from organic solution of the block copolymer by the diafiltration method. Amphiphilic merocyanine dyes (MDs) were self-assembled in the self-assembled copolymeric nanoparticles which provide a chiral microenvironment as red-shifted...
Thermoplastic hydrogels based on hexablock copolymer composed of poly(γ-benzyl l-glutamate) (PBLG) as the biodegradable and hydrophobic part and poly(ethylene oxide) (PEO) as the swellable and hydrophilic part were synthesized by polymerization of γ-benzyl l-glutamate N-carboxyanhydride (BLG–NCA) initiated by bis[poly(ethyleneoxide)bis(amine)]. From infrared measurement in the solid state, the polypeptide...
Diblock copolymers composed of poly(γ-benzyl l-glutamate) (PBLG) as the hydrophobic component and poly(ethylene oxide) (PEO) as the hydrophilic component were obtained by the polymerization of γ-benzyl l-glutamate N-carboxyanhydride, initiated by the primary amino end group of the α-methoxy-ω-amino PEO. Nanoparticles are formed from an organic solution of the block copolymers by the diafiltration...
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