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The cis‐1,1,1,4,4,4‐hexafluoro‐2‐butene (DR‐2 or HFO‐1336mzz(Z)) is a novel environmentally friendly working fluid with appropriate physicochemical characteristics. The present work firstly investigated the decomposition mechanism and thermal stability of DR‐2 in a oxygen (O2)‐containing atmosphere at high temperature experimentally. The oxidative degradation features of DR‐2 were explored at the...