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We demonstrate a novel preparative strategy for the well-controlled MnCo2O4.5@MnO2 hierarchical nanostructures. Both δ-MnO2 nanosheets and α-MnO2 nanorods can uniformly decorate the surface of MnCo2O4.5 nanowires to form core–shell heterostructures. Detailed electrochemical characterization reveals that MnCo2O4.5@δ-MnO2 pattern exhibits not only high specific capacitance of 357.5 F g−1 at a scan rate...
The Mn dissolution and capacity losses of spinel electrodes in lithium-ion cells with the various electrolyte solutions of LiPF 6 , LiClO 4 , LiBF 4 and LiCF 3 SO 3 , in ethylene carbonate–dimethyl carbonate (EC–DMC) were studied using rotating ring–disk collection experiments. The cyclic voltammograms are similar at high scan rates for all electrolytes. Electrodes...
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