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Obstructed decomposition of methanol by CO on Pt nanoclusters deposited from the vapor onto thin-film Al 2 O 3 /NiAl(100) was studied with various surface probe techniques. The Pt clusters had mean diameter about 2.3nm and height about 0.4nm, and grew with phase fcc and primarily in the (111) orientation. CO adsorbed molecularly on the Pt clusters to saturate the sites atop Pt, and...
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