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Palladium-catalyzed allylic amination is an important synthetic reaction that is also frequently used as a benchmark for the design and evaluation of new chiral ligands. The effect of reversible nucleophilic addition on the reaction of benzylamine with (E)-1,3-diphenylallyl ethyl carbonate (1) in CH2Cl2 was examined with 12 different chiral ligands across a range of scaffolding types. In 8 out of...
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