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The synthesis and catalytic performance of novel cis-dioxo-Mo(VI) complexes containing simple ONO tridentate Schiff base ligands in the epoxidation of various olefins using tert-butyl hydroperoxide in desired times with excellent chemo- and stereoselectivity have been described. The study of turnover numbers and the UV–Vis spectra of the Mo complexes in the present epoxidation system indicate well...
A new dioxo-molybdenum(VI) complex [MoO 2 (L)(CH 3 OH)] has been synthesized, using 2-[(2-hydroxypropylimino)methyl]phenol as tridentate ONO donor Schiff base ligand (H 2 L) and MoO 2 (acac) 2 . A monoclinic space group P2 1 /c was determined by X-ray crystallography from single-crystal data of this complex. The high catalytic activity of this new Schiff...
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