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Si–air battery (SAB) comprising of Si nanowire (SiNW) anode and alkaline solution and showing a working voltage of ca. 1.2V is investigated to elucidate the origin of superior discharge performance of the nanostructured Si anode to that of a planar Si anode. The SiNWs are found to transform into Si nanopyramids (SiNPs) upon immersion in the alkaline solution or when subjected to SAB discharge. In...
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