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Dodecamere und pentamere Cluster … …, (H2O2)12 und (H2O2)5, wurden in Kristallstrukturen der Peroxosolvate von 2‐Aminonicotinsäure und Lidocain‐N‐oxid entdeckt. In ihrer Zuschrift auf S. 15443 zeigen P. V. Prikhodchenko, A. V. Churakov et al., dass die Selbstorganisation der Wasserstoffperoxid‐Moleküle keine speziellen Bedingungen erfordert. Große H2O2‐Cluster können entstehen, wenn sich Freiraum...
Peroxosolvates of 2‐aminonicotinic acid (I) and lidocaine N‐oxide (II) including the largest insular hydrogen peroxide clusters were isolated and their crystal structures were determined by single‐crystal X‐ray diffraction. An unprecedented dodecameric hydrogen peroxide insular cluster was found in I. An unusual cross‐like pentameric cluster was observed in the structure of II. The topology of the...
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