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Cathodic electrodeposition of composite zirconia-poly(diallyldimethylammonium chloride) (PDDA) films was performed from ZrOCl 2 solutions in a mixed methanol–water solvent containing PDDA. The electrodeposition method is based on the electrosynthesis of zirconia and electrophoresis of PDDA. The method enables the room-temperature electrosynthesis of crystalline zirconia nanoparticles in the...
Thin films of zirconia and an organoceramic composite consisting of zirconium hydroxide and poly(diallyldimethylammonium chloride) (PDDA) were obtained via cathodic electrodeposition. Films up to 10-μm-thick were obtained on Ni and porous Ni-yttria-stabilized zirconia (YSZ) cermet substrates. By varying the current density, concentrations of PDDA and zirconium salt, the amount of the deposited material...
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