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It is widely known that addition of a radical species to the sulfur atom of a reduced sulfur molecule results in formation of a two-center three-electron (2c-3e) bond, but relatively few investigations have been reported for the 2c-3e bond between the NO 3 radical and a sulfur molecule. This article presents results of gas-phase DFT and ab initio investigations on the 2c-3e type adducts of...
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