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Atomic-like Auger electron emission was observed in resonant excitation of F1s electron into the σCSF* molecular orbital of CF 3 SF 5 . This finding means that an SF bond forming the CSF linear skeleton in the ground state dissociates in the order of femto-seconds. The Auger electron emitted from the F atom showed a Doppler shift by using angle-resolved photoelectron spectroscopy....
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