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A new benzyl-substituted bis-benzimidazolium derivative featuring a para-xylene spacer (1) has been prepared. Reaction of 1 with Ag 2 O in stoichiometric ratio followed by metathesis with KPF 6 yielded a dinuclear silver-carbene complex 2. The benzimidazolium ligands in 2 are arranged in a head-to-head fashion (2:2), spanning a short AgAg separation of 3.10(6) Å between two complex...
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