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The catalytic activity of two CNC palladium pincer complexes is evaluated in two fundamental CC bond‐forming reactions: MizorokiHeck and Sonogashira cross‐couplings. After several optimization attempts and a brief comparison with a PCN pincer catalyst, a number of arylated alkenes and diarylethynes are synthesized by procedures based on the catalytic use of the above mentioned CNC Pd pincers in...
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