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In this study, three trivalent Mn (oxyhydr)oxides, bixbyite (α-Mn2O3), hausmannite (Mn3O4) and manganite (γ-MnOOH) were synthesized and used as persulfate (PS) activators in phenol oxidation. Of these three Mn (oxyhydr)oxides, only γ-MnOOH shows a good catalytic activity in PS activation with more than 80% phenol oxidized within 360min in the full pH range. With increasing concentrations of PS and...
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