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The newly synthesized mer-trans-[RuCl2(OH2)(PTA)3] (1) is the first compound isolated in solid state containing the Ru(PTA)3-fragment (PTA=1,3,5-triaza-7-phosphatricyclo[3.3.1.13,7]decane). Dissolution of 1 in aqueous HCl leads to mer-[RuCl3(HPTA)3]Cl2 (2) which is stable in the dark but is transformed into fac-[RuCl3(HPTA)3]Cl2 (3) under visible light. Irradiation with visible light of an aqueous...
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