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The objective was to determine whether the initial pregastric lipase catalyzed hydrolysis of a triacylglycerol to 1,2(2,3)-diacylglycerol was a consequence of sn-specific hydrolysis. The identity of the reaction products for the enzyme-assisted hydrolysis and uncatalyzed acyl-transfer reaction sequence of tributyrylglycerol was assigned by 13C nuclear magnetic resonance. The optical activity of the...
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