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DSC measurements have been performed on human superoxide dismutase (HSOD) and on its mutants on the Glu132 and Glu133 residues which have been alternatively modified to a Gln residue. In both cases, the substitution has dramatic effects on the thermal denaturation of HSOD as evidenced by the calorimetric experiments. In particular, replacement of the Glu residue in position 132 seems to have a greater...
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