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Novel heterostructured Ag@AgI/ZnS microspheres were fabricated through a soft chemical route using polyvinylpyrrolidone (PVP). Their formation was confirmed by SEM, TEM, XRD, XPS, and FTIR analyses, which revealed that the Ag@AgI/ZnS nanocomposites comprised Ag, AgI, and ZnS nanoparticles. Luminescence quenching in the Ag@AgI/ZnS nanocomposites indicated that the hetero-junction between Ag@AgI and...
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